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depends, i've never seen em are they textured or pretty smooth. if they are pretty smooth i'd think with a bit of light sanding you could easily paint them. I painted the flares on my wrangler because they were faded and now they look great and that was like six months ago and still all good.
IIRC the powerwagon flares are textured and would take a lot of labor to get them paint ready, DC Parts sells a paintable fender flair, easy to do... sand a bit, degrease, seal, paint... I did it myself and it turned out A+.