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If you have to have them painted then just do what Matt said and sand and paint. if you want EASY then just plasti dip them.
Matt- I'll be doing this very soon. How do your wheels hold up in the winter?
CJS4444- Did you paint or plasti dip your gas cap?
you mean powdercoat? Mine have been great so far, and salt/acid cannot do anything to a powdercoated rim because the thickness of the plastic coat acts like a barrier