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How along was your last tune up? Mine threw that code, I did a tune up cleaned the throttle body intake and ran some Lucas fuel cleaner and icleared the code and never came back. Change the o2 sensors, that could be the cause if not its the cat converter
to my knowledge the 5.9 only came with 2 O2 sensors, one pre cat sensor and one post cat sensor, change the post cat sensor, (the one AFTER the cat, farthest away from the engine)